Journal of the Society of Motion Picture Engineers (1930-1949)

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July, 1945 APPLICATION OF THE POLAROGRAPH 27 Silver. — A well-defined diffusion current is obtained from the reduction of silver thiosulfate ion from a solution of sodium thiosulfate.11 This wave starts from 0 applied potential. To assure a large concentration of thiosulfate ions, 10 ml of 0.1 TV sodium thiosulfate were used as the base electrolyte. One ml of the unknown fixing bath and 3 drops of 6 per cent gelatin to prevent maxima were added. This solution was diluted to 20 ml and placed in the elec 600 500 400 300 200 +.8 -.6 +4 t2 0 -2 -4 -.6 -.8 -1.0-1.2 VOLTS FIG. 4. Silver. trolysis cell for polarographic determination. A typical wave is shown in Fig. 4. It is advisable to make a determination on a blank solution, so that any current carried by the base solution alone may be subtracted from the current carried by the silver and the base solution. To determine the diffusion current constant /, known quantities of silver nitrate were added to a fixing bath and the diffusion currents were measured as described above. The diffusion current constants thus found are reported in Table 1. The average value was used in analysis.