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1949
PHOTOGRAPHIC DEVELOPERS
275
These two absorbancies fix the point X on Fig. 2, which corresponds to an Elon concentration of 2.24 grams per liter and a hydroquinone concentration of 1.47 grams per liter.
ANALYSIS OF USED DEVELOPERS
Extraction of Elon and Hydroquinone with Ethyl Acetate
Preliminary investigations showed that Elon and hydroquinone could be completely extracted from a developer solution at pR 8.0 to 8.5 by the use of a solvent such as ethyl acetate. Ethyl acetate was chosen because of its low toxicity, small fire hazard, and its relatively low absorbancy in the region of 270 to 290 millimicrons.
Extraction of Oxidation Products
Hydroquinone monosulfonate, quinhydrone, quinone, and Elon monosulfonate were selected as compounds that exist or would be converted into compounds that might exist in a used developer solution.12
A mix was prepared containing 3.88 grams per liter of sodium hydroquinone monosulfonate and no Elon or hydroquinone. The absorption curves were determined before and after extraction as shown in Fig. 3, curves A and B. Curve B has been adjusted to compensate for the dilution brought about by the pH. adjustment that was necessary to insure complete extraction. It is concluded from the curves A and B in Fig. 3 that the amount of hydroquinone monosulfonate extracted is negligible. The small difference between the curves may possibly be due to the presence of a small amount of hydroquinone in the sodium hydroquinone monosulfonate.
In this study, this practice was followed for all curves obtained after extraction.
240 260 280 3OO 320
with and
Wavelength mp
Fig. 3 — Extraction study hydroquinone monosulfonate hydroquinone.
A, hydroquinone monosulfonate.
B, solution A after extraction.
C, solution A with hydroquinone added.
D, solution C after extraction.